Brown University
Chemistry

Recent papers

Celebrating Kenneth D. Karlin for his ACS Award for Distinguished Service in the Advancement of Inorganic Chemistry
Journal of Inorganic Biochemistry 2023, 241.
Journal of Inorganic Biochemistry – Karlin Special Issue
Journal of Inorganic Biochemistry 2023, 241.
Free Trions with Near-Unity Quantum Yield in Monolayer MoSe 2
ACS Nano 2022, 16 (1), 140–147.
Exciton-coupled coherent magnons in a 2D semiconductor
Nature 2022, 609 (7926), 282–286.
Disorder of excitons and trions in monolayer MoSe 2
Journal of Chemical Physics 2022, 157 (21).
Dioxygen reactivity of a biomimetic [4Fe-4S] compound exhibits [4Fe-4S] to [2Fe-2S] cluster conversion
Journal of Inorganic Biochemistry 2022, 228.
Dissecting Interlayer Hole and Electron Transfer in Transition Metal Dichalcogenide Heterostructures via Two-Dimensional Electronic Spectroscopy
Nano Letters 2021, 21 (11), 4738–4743.
Diffusivity Reveals Three Distinct Phases of Interlayer Excitons in MoSe2/WSe2 Heterobilayers
Physical Review Letters 2021, 126 (10).
The Biologically Relevant Coordination Chemistry of Iron and Nitric Oxide: Electronic Structure and Reactivity
Chemical Reviews 2021, 121 (24), 14682–14905.
Generation of H 2 S from Thiol-Dependent NO Reactivity of Model [4Fe-4S] Cluster and Roussin's Black Anion
Inorganic Chemistry 2021, 60 (21), 15910–15917.
Controlled Protonation of [2Fe-2S] Leading to MitoNEET Analogues and Concurrent Cluster Modification
Inorganic Chemistry 2021, 60 (21), 16074–16078.
Leveraging autocatalytic reactions for chemical domain image classification
Chemical Science 2021, 12 (15), 5464–5472.
Implementing parallel arithmetic via acetylation and its application to chemical image processing
Proceedings of the Royal Society A: Mathematical, Physical and Engineering Sciences 2021, 477 (2248).
Topology, Distance, and Orbital Symmetry Effects on Electronic Spin-Spin Couplings in Rigid Molecular Systems: Implications for Long-Distance Spin-Spin Interactions
Journal of Physical Chemistry A 2020, 124 (37), 7411–7415.
Correlated electronic phases in twisted bilayer transition metal dichalcogenides
Nature Materials 2020, 19 (8), 861–866.
Excitons in strain-induced one-dimensional moiré potentials at transition metal dichalcogenide heterojunctions
Nature Materials 2020, 19 (10), 1068–1073.
Author Correction: Excitons in strain-induced one-dimensional moiré potentials at transition metal dichalcogenide heterojunctions (Nature Materials, (2020), 19, 10, (1068-1073), 10.1038/s41563-020-073
Nature Materials 2020, 19 (10), 1124–0.
Visualization of moiré superlattices
Nature Nanotechnology 2020, 15 (7), 580–584.
Electronic structure and photophysics of a supermolecular iron complex having a long MLCT-state lifetime and panchromatic absorption
Proceedings of the National Academy of Sciences of 2020, 117 (34), 20430–20437.
Disassembling 2D van der Waals crystals into macroscopic monolayers and reassembling into artificial lattices
Science 2020, 367 (6480), 903–906.
Multicomponent molecular memory
Nature Communications 2020, 11 (1).
Principles of Information Storage in Small-Molecule Mixtures
IEEE Transactions on Nanobioscience 2020, 19 (3), 378–384.
Optical generation of high carrier densities in 2D semiconductor heterobilayers
Science Advances 2019, 5 (9).
Reactivity of a biomimetic W(iv) bis-dithiolene complex with CO 2 leading to formate production and structural rearrangement
Dalton Transactions 2019, 48 (47), 17441–17444.
Carrier Dynamics Engineering for High-Performance Electron-Transport-Layer-free Perovskite Photovoltaics
Chem 2018, 4 (10), 2405–2417.
Solvent- A nd wavelength-dependent photoluminescence relaxation dynamics of carbon nanotube sp 3 defect states
ACS Nano 2018, 12 (8), 8060–8070.
Quantitative Evaluation of Optical Free Carrier Generation in Semiconducting Single-Walled Carbon Nanotubes
Journal of the American Chemical Society 2018, 140 (44), 14619–14626.
Dynamics of charged excitons in electronically and morphologically homogeneous single-walled carbon nanotubes
Proceedings of the National Academy of Sciences of 2018, 115 (4), 674–679.
Lewis Acid Assisted Nitrate Reduction with Biomimetic Molybdenum Oxotransferase Complex
Inorganic Chemistry 2018, 57 (5), 2594–2602.
Molecular Road Map to Tuning Ground State Absorption and Excited State Dynamics of Long-Wavelength Absorbers
Journal of the American Chemical Society 2017, 139 (46), 16946–16958.
Additive engineering for high-performance room-temperature-processed perovskite absorbers with micron-size grains and microsecond-range carrier lifetimes
Energy and Environmental Science 2017, 10 (11), 2365–2371.
Controlling the excited-state dynamics of low band gap, near-infrared absorbers: Via proquinoidal unit electronic structural modulation
Chemical Science 2017, 8 (9), 5889–5901.
First-order hyperpolarizabilities of chiral, polymer-wrapped single-walled carbon nanotubes
Chemical Communications 2016, 52 (82), 12206–12209.
Unusual Synthetic Pathway for an {Fe(NO) 2 } 9 Dinitrosyl Iron Complex (DNIC) and Insight into DNIC Electronic Structure via Nuclear Resonance Vibrational Spectroscopy
Inorganic Chemistry 2016, 55 (11), 5485–5501.
A Peroxynitrite Dicopper Complex: Formation via Cu-NO and Cu-O 2 Intermediates and Reactivity via O-O Cleavage Chemistry
Journal of the American Chemical Society 2016, 138 (49), 16148–16158.
Unambiguous Diagnosis of Photoinduced Charge Carrier Signatures in a Stoichiometrically Controlled Semiconducting Polymer-Wrapped Carbon Nanotube Assembly
Angewandte Chemie - International Edition 2015, 54 (28), 8133–8138.
Near-infrared-to-visible photon upconversion enabled by conjugated porphyrinic sensitizers under low-power noncoherent illumination
Journal of Physical Chemistry A 2015, 119 (22), 5642–5649.
Synthetic Modeling Chemistry of Iron-Sulfur Clusters in Nitric Oxide Signaling
Accounts of Chemical Research 2015, 48 (8), 2453–2461.
New Synthetic Routes to Iron-Sulfur Clusters: Deciphering the Repair Chemistry of [2Fe-2S] Clusters from Mononitrosyl Iron Complexes
Inorganic Chemistry 2015, 54 (22), 10559–10567.
Transformation of a mononitrosyl iron complex to a [2Fe-2S] cluster by a cysteine analogue
Journal of the American Chemical Society 2014, 136 (20), 7229–7232.
Nitric oxide reactivity of [2Fe-2S] clusters leading to H 2 S generation
Journal of the American Chemical Society 2014, 136 (34), 11874–11877.
Coordination-triggered NO release from a dinitrosyl iron complex leads to anti-inflammatory activity
Chemical Science 2014, 5 (6), 2374–2378.

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